Heat Capacity and Calorimetry

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AP Chemistry › Heat Capacity and Calorimetry

Questions 1 - 10
1

A $40.0,\text{g}$ sample of aluminum is heated, and its temperature increases from $25.0^\circ\text{C}$ to $50.0^\circ\text{C}$. The specific heat capacity of aluminum is $0.900,\text{J},(\text{g}\cdot{}^\circ\text{C})^{-1}$. What is the heat absorbed by the aluminum sample, $q$?

+90.0 J

$+1.80×10^3$ J

+900 J

−900 J

+360 J

Explanation

This problem tests the skill of heat capacity and calorimetry. For aluminum heating from 25.0°C to 50.0°C, we use q = mcΔT with m = 40.0 g, c = 0.900 J/(g·°C), and ΔT = 50.0°C - 25.0°C = 25.0°C. Calculating: q = (40.0 g)(0.900 J/(g·°C))(25.0°C) = 900 J. Since temperature increases, the aluminum absorbs heat, so q = +900 J. A common error is using only one temperature value (like 25.0°C) instead of calculating the temperature difference, which would give +360 J. Always calculate ΔT as the difference between final and initial temperatures before substituting into q = mcΔT.

2

A reaction occurs in a coffee-cup calorimeter and causes the temperature of the solution to decrease from $26.0^\circ\text{C}$ to $23.0^\circ\text{C}$. The total heat capacity of the solution is $C_{\text{soln}}=500,\text{J},/,^\circ\text{C}$. What is the heat transferred for the solution, $q_{\text{soln}}$?

$−1.67×10^2$ J

$+1.00×10^3$ J

$−5.00×10^2$ J

$+1.50×10^3$ J

$−1.50×10^3$ J

Explanation

This problem tests the skill of heat capacity and calorimetry. For a solution with total heat capacity C_soln = 500 J/°C cooling from 26.0°C to 23.0°C, we use q = C × ΔT. With ΔT = 23.0°C - 26.0°C = -3.0°C, we get: q = (500 J/°C)(-3.0°C) = -1500 J = -1.50×10³ J. The negative sign indicates the solution releases heat as it cools. A common error is using the absolute value of ΔT (3.0°C), which would incorrectly give +1.50×10³ J, missing the direction of heat flow. When using total heat capacity, apply q = C × ΔT directly and preserve the sign of ΔT.

3

A 200. g sample of a solution in a coffee-cup calorimeter absorbs $+3,600\ \text{J}$ of heat. The specific heat capacity of the solution is $4.0\ \text{J},\text{g}^{-1},^{\circ}\text{C}^{-1}$. What is the temperature change, $\Delta T$, of the solution?

-4.5 °C

+0.45 °C

+9.0 °C

+4.5 °C

+18.0 °C

Explanation

This question tests the skill of heat capacity and calorimetry. The temperature change is determined by rearranging q = m c ΔT to ΔT = q / (m c), where q is positive since the solution absorbs heat. The system is the solution, and this equation models the temperature rise due to energy input. With q = +3,600 J, ΔT = 3,600 J / (200 g × 4.0 J g⁻¹ °C⁻¹) = +4.5°C, correctly calculating the change. A tempting distractor is choice A, +18.0°C, which occurs from the misconception of forgetting to include the mass in the denominator. Always rearrange the heat capacity formula carefully and double-check units for consistency.

4

A 40.0 g sample of a solid is heated and its temperature increases by $30.0^{\circ}\text{C}$. The specific heat capacity of the solid is $1.2\ \text{J},\text{g}^{-1},^{\circ}\text{C}^{-1}$. What is the heat absorbed by the solid, $q$?

+900 J

+1,440 J

+144 J

+3,600 J

-1,440 J

Explanation

This question tests the skill of heat capacity and calorimetry. The heat absorbed by the solid is q = m c ΔT, where ΔT is positive for the temperature increase of 30.0°C. The system is the solid, absorbing heat, and the equation models this energy input. Thus, q = 40.0 g × 1.2 J g⁻¹ °C⁻¹ × 30.0°C = +1,440 J, accurately depicting the process. A tempting distractor is choice C, -1,440 J, stemming from the misconception of assigning a negative q to heat absorption. Identify the system and heat direction first, then use q = m c ΔT with appropriate values.

5

A calorimeter has an effective heat capacity of $C = 80\ \text{J}/^{\circ}\text{C}$. In a trial, the calorimeter releases $-1,600\ \text{J}$ of heat to the surroundings. What is the temperature change, $\Delta T$, of the calorimeter?

+20 °C

-1,280 °C

-12.5 °C

+12.5 °C

-20 °C

Explanation

This question tests the skill of heat capacity and calorimetry. The temperature change for the calorimeter is ΔT = q / C, where q is negative because it releases heat. The system is the calorimeter, and this rearranged equation models the cooling due to energy loss. With q = -1,600 J, ΔT = -1,600 J / 80 J °C⁻¹ = -20°C, indicating a temperature decrease. A tempting distractor is choice A, +20°C, which comes from the misconception of ignoring the negative sign of q. Confirm the sign of q based on heat flow direction before solving for ΔT.

6

A student adds 200. g of water to a beaker and supplies heat, causing the water temperature to rise from 15.0°C to 18.0°C. Assume $c_{\text{water}} = 4.18\ \text{J},(\text{g}\cdot{}^\circ\text{C})^{-1}$. What is the heat absorbed by the water, $q$?

$+1.25×10^3$ J

$+5.02×10^3$ J

$−2.51×10^3$ J

$+2.51×10^3$ J

+836 J

Explanation

This question tests the skill of heat capacity and calorimetry. The system is the water in the beaker, which absorbs heat, increasing its temperature from 15.0°C to 18.0°C, so ΔT is +3.0°C. The heat absorbed is calculated with q = m c ΔT, using m = 200 g and c = 4.18 J/(g·°C), yielding q = 200 × 4.18 × 3.0 = +2508 J, or $+2.51×10^3$ J. This equation accurately models the energy transfer as it incorporates the mass-specific response to heat input via specific heat capacity. A tempting distractor is B (+836 J), which results from the misconception of using only one-third of the mass or forgetting to multiply by ΔT fully in q = m c ΔT. Always double-check units and ensure all variables in q = m c ΔT are correctly plugged in for accurate heat calculations.

7

A student places 50.0 g of liquid water in a coffee-cup calorimeter. The temperature of the water increases from 22.0°C to 28.0°C. Assume the water absorbs all the heat released and that the specific heat capacity of water is $4.18\ \text{J},(\text{g}\cdot{}^\circ\text{C})^{-1}$. What is the heat absorbed by the water, $q_{\text{water}}$?

$+1.25×10^3$ J

$+2.51×10^3$ J

$−2.51×10^3$ J

$−1.25×10^3$ J

$+5.02×10^2$ J

Explanation

This question tests the skill of heat capacity and calorimetry. The system here is the water in the calorimeter, which absorbs heat, leading to a temperature increase from 22.0°C to 28.0°C, so ΔT is +6.0°C. The heat absorbed by the water is calculated using the equation q = m c ΔT, where m is 50.0 g and c is 4.18 J/(g·°C), resulting in q = 50.0 × 4.18 × 6.0 = +1254 J, or $+1.25×10^3$ J. This equation models the energy transfer accurately because it accounts for the mass, specific heat, and temperature change, assuming no heat loss to surroundings as stated. A tempting distractor is B $(−1.25×10^3$ J), which arises from the misconception of assigning a negative sign to heat absorbed, confusing the sign convention where positive q indicates heat gained by the system. To solve similar problems, always calculate ΔT as T_final − T_initial and assign the sign based on whether the system is absorbing or releasing heat.

8

A student cools $200.\ \text{g}$ of water from $35.0^\circ\text{C}$ to $25.0^\circ\text{C}$. Assume $c_{\text{water}} = 4.18\ \text{J},\text{g}^{-1},\text{^\circC}^{-1}$. What is the heat transferred for the water, $q_{\text{water}}$?

−8.36\ $\text{kJ}$

+0.836\ $\text{kJ}$

−83.6\ $\text{kJ}$

−0.836\ $\text{kJ}$

+8.36\ $\text{kJ}$

Explanation

This problem tests the skill of heat capacity and calorimetry. The water is cooled from 35.0°C to 25.0°C, so it releases heat and q will be negative. Using q = mcΔT: q = (200. g)(4.18 J·g⁻¹·°C⁻¹)(25.0°C - 35.0°C) = (200.)(4.18)(-10.0) = -8360 J = -8.36 kJ. The negative sign correctly indicates heat released by the water as it cooled. A common error would be to choose +8.36 kJ (choice A), forgetting that cooling processes have negative q values. Always determine the sign of q by considering whether the substance gains heat (positive q) or loses heat (negative q) based on the temperature change.

9

A calorimeter has a heat capacity of $C = 120\ \text{J},\text{^\circC}^{-1}$. If the calorimeter absorbs $600\ \text{J}$ of heat, what is the resulting temperature change, $\Delta T$, of the calorimeter?

+5.00\ ^\circ$\text{C}$

+50.0\ ^\circ$\text{C}$

−5.00\ ^\circ$\text{C}$

+720\ ^\circ$\text{C}$

+0.200\ ^\circ$\text{C}$

Explanation

This problem tests the skill of heat capacity and calorimetry. For a calorimeter with heat capacity C, we use q = CΔT and rearrange to find ΔT = q/C. Given q = 600 J and C = 120 J·°C⁻¹, we calculate: ΔT = 600 J / 120 J·°C⁻¹ = 5.00°C. Since heat was absorbed (positive q), the temperature increased by 5.00°C. A common mistake would be to select +0.200°C (choice A), which results from dividing C by q instead of q by C. When finding temperature change from heat and heat capacity, remember that ΔT = q/C, not C/q.

10

A $75.0\ \text{g}$ sample of aluminum is cooled from $100.0^\circ\text{C}$ to $40.0^\circ\text{C}$. The specific heat capacity of aluminum is $0.900\ \text{J},\text{g}^{-1},\text{^\circC}^{-1}$. What is the heat transferred for the aluminum sample, $q$?

+405\ $\text{J}$

+4.05\ $\text{kJ}$

−40.5\ $\text{kJ}$

−405\ $\text{J}$

−4.05\ $\text{kJ}$

Explanation

This problem tests the skill of heat capacity and calorimetry. The aluminum is cooled from 100.0°C to 40.0°C, so it releases heat and q will be negative. Using q = mcΔT: q = (75.0 g)(0.900 J·g⁻¹·°C⁻¹)(40.0°C - 100.0°C) = (75.0)(0.900)(-60.0) = -4050 J = -4.05 kJ. The negative sign correctly indicates heat released during cooling. A common error would be to choose +4.05 kJ (choice A), using the wrong sign by calculating ΔT as (100.0 - 40.0) instead of (final - initial). Always calculate ΔT as (Tfinal - Tinitial) to automatically get the correct sign for q.

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