Introduction to Acids and Bases

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AP Chemistry › Introduction to Acids and Bases

Questions 1 - 10
1

A student dissolves sodium acetate in water. Consider the reaction $\mathrm{CH_3COO^-(aq) + H_2O(l) \rightleftharpoons CH_3COOH(aq) + OH^-(aq)}$. In this reaction, $\mathrm{CH_3COO^-}$ acts as the

Brønsted–Lowry acid, because it donates $\mathrm{H^+}$ to water.

Brønsted–Lowry base, because it accepts $\mathrm{H^+}$ from water.

conjugate acid of $\mathrm{CH_3COOH}$.

spectator ion, because it does not change into a different species.

Lewis acid, because it donates an electron pair to water.

Explanation

This question tests introduction to acids and bases using the Brønsted-Lowry definition to identify bases as proton acceptors. In the reaction CH₃COO⁻(aq) + H₂O(l) ⇌ CH₃COOH(aq) + OH⁻(aq), the acetate ion CH₃COO⁻ gains a proton from water to become CH₃COOH, while water loses that proton to become OH⁻. Since CH₃COO⁻ accepts a proton, it acts as a Brønsted-Lowry base. Choice C (conjugate acid of CH₃COOH) is incorrect because CH₃COO⁻ is actually the conjugate base of CH₃COOH, not its conjugate acid. When analyzing acid-base reactions, track the proton transfer: the species gaining H⁺ is the base, the species losing H⁺ is the acid.

2

A student studies the reaction $\mathrm{H_2PO_4^-(aq) + H_2O(l) \rightleftharpoons HPO_4^{2-}(aq) + H_3O^+(aq)}$. Which species is the conjugate base of $\mathrm{H_2PO_4^-}$ in this reaction?

$\mathrm{H_2PO_4^-}$

$\mathrm{H_3O^+}$

$\mathrm{H_2O}$

$\mathrm{HPO_4^{2-}}$

$\mathrm{PO_4^{3-}}$

Explanation

This question tests introduction to acids and bases focusing on identifying conjugate base relationships. In the reaction H₂PO₄⁻(aq) + H₂O(l) ⇌ HPO₄²⁻(aq) + H₃O⁺(aq), H₂PO₄⁻ donates a proton to water, becoming HPO₄²⁻. The conjugate base of any acid is what remains after the acid loses one proton. Since H₂PO₄⁻ loses H⁺ to form HPO₄²⁻, HPO₄²⁻ is the conjugate base of H₂PO₄⁻. Choice E (PO₄³⁻) is incorrect because it would require losing two protons from H₂PO₄⁻, not just one. Remember that conjugate acid-base pairs always differ by exactly one proton, and the conjugate base has one fewer H⁺ than its conjugate acid.

3

A student observes the reaction $\mathrm{HSO_4^-(aq) + H_2O(l) \rightleftharpoons SO_4^{2-}(aq) + H_3O^+(aq)}$. Which statement best describes $\mathrm{HSO_4^-}$ in this reaction?

$\mathrm{HSO_4^-}$ is a spectator ion and does not participate in proton transfer.

$\mathrm{HSO_4^-}$ is an Arrhenius base because it produces $\mathrm{H^+}$ in water.

$\mathrm{HSO_4^-}$ acts as a Brønsted–Lowry acid because it donates $\mathrm{H^+}$.

$\mathrm{HSO_4^-}$ acts as a Brønsted–Lowry base because it accepts $\mathrm{H^+}$.

$\mathrm{HSO_4^-}$ is neither an acid nor a base because it is negatively charged.

Explanation

This question assesses the skill of introduction to acids and bases, using the Brønsted–Lowry definition of acids as proton donors. In the reaction HSO₄⁻(aq) + H₂O(l) ⇌ SO₄²⁻(aq) + H₃O⁺(aq), proton transfer is from HSO₄⁻ to H₂O. HSO₄⁻ donates H⁺ to become SO₄²⁻, confirming its role as the acid. This matches choice B, describing HSO₄⁻ as a Brønsted–Lowry acid. A tempting distractor is A, suggesting it acts as a base by accepting H⁺, but the reaction shows donation, not acceptance. Always track H⁺ transfer; the donor is the acid, and it forms its conjugate base.

4

In water, hydrogen sulfite reacts as shown: $\mathrm{HSO_3^-(aq) + H_2O(l) \rightleftharpoons SO_3^{2-}(aq) + H_3O^+(aq)}$. Which pair is a conjugate acid–base pair in this reaction?

$\mathrm{H_3O^+}$ and $\mathrm{SO_3^{2-}}$

$\mathrm{H_2O}$ and $\mathrm{SO_3^{2-}}$

$\mathrm{HSO_3^-}$ and $\mathrm{SO_3^{2-}}$

$\mathrm{H_2O}$ and $\mathrm{HSO_3^-}$

$\mathrm{HSO_3^-}$ and $\mathrm{H_3O^+}$

Explanation

This question tests introduction to acids and bases focusing on conjugate acid-base pairs in the Brønsted-Lowry framework. In the reaction HSO₃⁻(aq) + H₂O(l) ⇌ SO₃²⁻(aq) + H₃O⁺(aq), a conjugate pair differs by exactly one H⁺. HSO₃⁻ loses one H⁺ to become SO₃²⁻, making HSO₃⁻/SO₃²⁻ a conjugate acid-base pair (HSO₃⁻ is the acid, SO₃²⁻ is its conjugate base). Similarly, H₂O gains one H⁺ to become H₃O⁺, making H₂O/H₃O⁺ the other conjugate pair. Students might incorrectly choose option B (H₃O⁺ and SO₃²⁻) because these are both products, but they don't form a conjugate pair since they don't differ by exactly one proton. The strategy is to find species that differ by exactly one H⁺, where one is a reactant and the other is a product.

5

A student mixes two aqueous solutions and the net ionic equation is $\mathrm{H^+(aq) + F^-(aq) \rightarrow HF(aq)}$. In this reaction, $\mathrm{F^-}$ is acting as

a conjugate acid because it forms $\mathrm{HF}$

an Arrhenius acid because it produces $\mathrm{H^+}$

a Brønsted–Lowry acid because it donates $\mathrm{H^+}$

a Brønsted–Lowry base because it accepts $\mathrm{H^+}$

a spectator ion because it is a halide

Explanation

This question assesses the skill of introduction to acids and bases, applying the Brønsted–Lowry definition where a base accepts a proton. In the reaction H⁺(aq) + F⁻(aq) → HF(aq), proton transfer is to F⁻ from H⁺. F⁻ accepts the H⁺ to form HF, making it the base. This determines choice B as correct. A tempting distractor is A, suggesting acid behavior, but no proton is donated by F⁻ here. Always track H⁺ transfer; the acceptor in the reaction is the base, forming its conjugate acid.

6

A student observes the reaction $\mathrm{HS^-(aq) + H_2O(l) \rightleftharpoons H_2S(aq) + OH^-(aq)}$. In the forward direction, water is best classified as which of the following?

A Brønsted–Lowry acid

A Brønsted–Lowry base

A spectator species

A conjugate base

A Lewis base because it accepts an electron pair from $\mathrm{HS^-}$

Explanation

This question tests introduction to acids and bases by classifying water's role using Brønsted-Lowry definitions. In the reaction HS⁻(aq) + H₂O(l) ⇌ H₂S(aq) + OH⁻(aq), we track proton movement in the forward direction. HS⁻ gains an H⁺ to become H₂S, while H₂O loses an H⁺ to become OH⁻. Since water donates a proton to HS⁻, water acts as a Brønsted-Lowry acid in this reaction. Students might choose option B thinking water always acts as a base, but water is amphiprotic and its role depends on what it's reacting with. The strategy is to check whether water gains H⁺ (base) or loses H⁺ (acid) by comparing H₂O to its product form.

7

A student dissolves sodium acetate in water and considers the reaction $\mathrm{CH_3COO^-(aq) + H_2O(l) \rightleftharpoons CH_3COOH(aq) + OH^-(aq)}$. Which species is the Brønsted–Lowry acid in the forward reaction?

$\mathrm{CH_3COOH}$

$\mathrm{CH_3COO^-}$

$\mathrm{Na^+}$

$\mathrm{H_2O}$

$\mathrm{OH^-}$

Explanation

This question tests introduction to acids and bases by identifying the Brønsted-Lowry acid in a hydrolysis reaction. In CH₃COO⁻(aq) + H₂O(l) ⇌ CH₃COOH(aq) + OH⁻(aq), we need to identify which species donates a proton in the forward reaction. CH₃COO⁻ gains an H⁺ to become CH₃COOH (acting as base), while H₂O loses an H⁺ to become OH⁻, making water the proton donor and thus the Brønsted-Lowry acid. Students might incorrectly choose CH₃COOH (option A) because acetic acid is typically an acid, but in this reaction CH₃COOH is the product formed when the base accepts a proton. Remember to focus on the forward reaction and identify which reactant loses H⁺—that's your acid.

8

In the reaction $\mathrm{HCl(aq) + H_2O(l) \rightarrow H_3O^+(aq) + Cl^-(aq)}$, which species is the conjugate base of the acid?

$\mathrm{HCl}$

$\mathrm{H_3O^+}$

$\mathrm{H^+}$

$\mathrm{H_2O}$

$\mathrm{Cl^-}$

Explanation

This question tests introduction to acids and bases focusing on conjugate base identification in the Brønsted-Lowry framework. In the reaction HCl + H₂O → H₃O⁺ + Cl⁻, we need to find what remains after the acid donates its proton. HCl donates an H⁺ to water, leaving behind Cl⁻, while water accepts that H⁺ to become H₃O⁺. The conjugate base of an acid is what remains after proton donation, so Cl⁻ is the conjugate base of HCl. A common mistake is choosing H₃O⁺ (choice A) because students associate it with acids, but H₃O⁺ is actually the conjugate acid of water in this reaction. To find a conjugate base, identify the acid first, then determine what species remains after it loses one H⁺.

9

A student writes the proton-transfer reaction $\mathrm{HNO_2(aq) + OH^-(aq) \rightarrow NO_2^-(aq) + H_2O(l)}$. Which species is the Brønsted–Lowry acid?

$\mathrm{OH^-}$

$\mathrm{H^+}$

$\mathrm{NO_2^-}$

$\mathrm{HNO_2}$

$\mathrm{H_2O}$

Explanation

This question assesses the skill of introduction to acids and bases, focusing on the Brønsted–Lowry acid as the proton donor. In the reaction HNO₂(aq) + OH⁻(aq) → NO₂⁻(aq) + H₂O(l), proton transfer occurs from HNO₂ to OH⁻. HNO₂ loses H⁺ to become NO₂⁻, confirming it as the acid. This determines choice D as correct. A tempting distractor is B, OH⁻, but it accepts the proton, acting as the base, not the acid. Always track H⁺ transfer; the acid is the species that donates the proton in the reaction.

10

A student mixes aqueous hydrofluoric acid with water: $\mathrm{HF(aq) + H_2O(l) \rightleftharpoons H_3O^+(aq) + F^-(aq)}$. Which pair represents a conjugate acid–base pair in this reaction?

$\mathrm{HF}$ and $\mathrm{F^-}$

$\mathrm{H_2O}$ and $\mathrm{F^-}$

$\mathrm{F^-}$ and $\mathrm{H_3O^+}$

$\mathrm{HF}$ and $\mathrm{H_3O^+}$

$\mathrm{H_2O}$ and $\mathrm{H_3O^+}$

Explanation

This question tests introduction to acids and bases focusing on identifying conjugate acid-base pairs. In the reaction HF(aq) + H₂O(l) ⇌ H₃O⁺(aq) + F⁻(aq), HF donates a proton to become F⁻, making HF/F⁻ a conjugate acid-base pair. Similarly, H₂O accepts a proton to become H₃O⁺, making H₂O/H₃O⁺ another conjugate pair. The question asks for one conjugate pair, and HF/F⁻ is correct because they differ by exactly one proton. Choice D (H₂O/H₃O⁺) is also a conjugate pair but represents the other half of the reaction. Remember that conjugate pairs always appear on opposite sides of the equation and differ by exactly one H⁺.

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