Oxidation-Reduction (Redox) Reactions
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AP Chemistry › Oxidation-Reduction (Redox) Reactions
Aluminum metal reacts with aqueous copper(II) chloride to produce aqueous aluminum chloride and copper metal, as shown:
$\mathrm{2,Al(s) + 3,CuCl_2(aq) \rightarrow 2,AlCl_3(aq) + 3,Cu(s)}$
How many electrons are transferred per aluminum atom that reacts?
6 electrons
4 electrons
1 electron
2 electrons
3 electrons
Explanation
This question assesses understanding of oxidation–reduction (redox) reactions. To determine electrons transferred per Al atom, assign oxidation numbers: Al(s) is 0, Cu in CuCl₂(aq) is +2 (Cl -1 each), Al in AlCl₃(aq) is +3, Cu(s) is 0. Each Al atom's oxidation number increases from 0 to +3, losing 3 electrons, while Cu decreases from +2 to 0, gaining 2 electrons; the balanced equation shows 2 Al and 3 Cu, so total 6 electrons transferred (3 per Al times 2). It's 3 electrons per aluminum atom. A tempting distractor is 2 electrons, but that's per Cu, not Al—a common error is confusing per atom with total transfer without balancing. Oxidation is loss of electrons; reduction is gain of electrons—track oxidation number changes per atom and use coefficients for total electrons.
Hydrogen peroxide can react with iodide ions in acidic solution to produce iodine and water:
$\text{H}_2\text{O}_2(aq) + 2\text{I}^-(aq) + 2\text{H}^+(aq) \rightarrow \text{I}_2(aq) + 2\text{H}_2\text{O}(l)$
Which species is reduced?
H2O(l)
I2(aq)
H2O2(aq)
I−(aq)
H+(aq)
Explanation
This question tests understanding of oxidation-reduction (redox) reactions. In H₂O₂(aq) + 2I⁻(aq) + 2H⁺(aq) → I₂(aq) + 2H₂O(l), iodide (I⁻) goes from -1 to 0 in I₂ (loses electrons, is oxidized), while oxygen in H₂O₂ has oxidation number -1 (unusual for oxygen) and becomes -2 in H₂O (gains electrons, is reduced). To verify O in H₂O₂: 2(+1) + 2(O) = 0, so O = -1. The species being reduced is H₂O₂. A common error is thinking I⁻ is reduced because it forms I₂, but forming a diatomic molecule from ions involves electron loss. Remember: reduction is gain of electrons (decrease in oxidation number), and peroxides have oxygen at -1.
A student adds aluminum metal to an aqueous solution of silver nitrate, producing silver metal:
$\text{Al}(s) + 3\text{AgNO}_3(aq) \rightarrow \text{Al(NO}_3)_3(aq) + 3\text{Ag}(s)$
How many electrons are transferred per aluminum atom in this reaction?
1
2
3
6
9
Explanation
This question tests understanding of oxidation–reduction (redox) reactions. Assign oxidation numbers: aluminum in Al(s) is 0, silver in AgNO₃ is +1, aluminum in Al(NO₃)₃ is +3, and silver in Ag(s) is 0. Aluminum's oxidation number increases from 0 to +3, indicating loss of 3 electrons per atom, while silver decreases from +1 to 0, showing gain of 1 electron per atom. Nitrate remains unchanged. A tempting distractor is 6, but that might come from doubling the electrons for the balanced equation; forgetting per-atom count is common. Oxidation is loss of electrons; reduction is gain of electrons—track oxidation numbers.
In aqueous solution, dichromate ions oxidize sulfite ions to sulfate ions:
$\text{Cr}_2\text{O}_7^{2-}(aq) + 3\text{SO}_3^{2-}(aq) + 8\text{H}^+(aq) \rightarrow 2\text{Cr}^{3+}(aq) + 3\text{SO}_4^{2-}(aq) + 4\text{H}_2\text{O}(l)$
Which species is oxidized?
$\text{Cr}^{3+}(aq)$
$\text{SO}_3^{2-}(aq)$
$\text{H}^+(aq)$
$\text{Cr}_2\text{O}_7^{2-}(aq)$
$\text{SO}_4^{2-}(aq)$
Explanation
This question tests understanding of oxidation–reduction (redox) reactions. Assign oxidation numbers: sulfur in $ \text{SO}_3^{2-} $ is +4, chromium in $ \text{Cr}_2\text{O}_7^{2-} $ is +6, sulfur in $ \text{SO}_4^{2-} $ is +6, and chromium in $ \text{Cr}^{3+} $ is +3. Sulfur's oxidation number increases from +4 to +6, indicating loss of electrons and oxidation, while chromium decreases from +6 to +3, showing gain of electrons and reduction. Hydrogen and oxygen numbers balance out. A tempting distractor is $ \text{Cr}_2\text{O}_7^{2-} $, but it is reduced, not oxidized; misidentifying the oxidized species is common in complex ions. Oxidation is loss of electrons; reduction is gain of electrons—track oxidation numbers.
In an acidic solution, iron(II) ions react with dichromate ions according to the overall reaction:
$6\text{Fe}^{2+}(aq) + \text{Cr}_2\text{O}_7^{2-}(aq) + 14\text{H}^+(aq) \rightarrow 6\text{Fe}^{3+}(aq) + 2\text{Cr}^{3+}(aq) + 7\text{H}_2\text{O}(l)$
Which species is reduced?
$Cr2O7^2$−(aq)
$Fe^3$+(aq)
H+(aq)
H2O(l)
$Fe^2$+(aq)
Explanation
This question tests understanding of oxidation-reduction (redox) reactions. In the reaction, Fe²⁺ changes to Fe³⁺ (oxidation number +2 to +3, loses electrons, is oxidized), while Cr in Cr₂O₇²⁻ has oxidation number +6 and becomes Cr³⁺ with oxidation number +3 (gains electrons, is reduced). To find Cr's oxidation number in Cr₂O₇²⁻: 2(Cr) + 7(-2) = -2, so Cr = +6. The species being reduced is Cr₂O₇²⁻ (dichromate ion). A common error is thinking H⁺ is reduced because it appears to form water, but H remains +1 throughout. Remember: reduction is gain of electrons (decrease in oxidation number), and track oxidation numbers systematically.
Aqueous dichromate reacts with iodide ions in acidic solution, producing chromium(III) ions and iodine:
$$\text{Cr}_2\text{O}_7^{2-}(aq)+14\text{H}^+(aq)+6\text{I}^-(aq)\rightarrow 2\text{Cr}^{3+}(aq)+3\text{I}_2(s)+7\text{H}_2\text{O}(l)$$
Which species is oxidized?
Cr$^{3+}$(aq)
H$^+$(aq)
H$_2$O(l)
Cr$_2$O$_7^{2-}$(aq)
I$^-$(aq)
Explanation
This question tests understanding of oxidation-reduction (redox) reactions. In this reaction, we track oxidation numbers: Cr in Cr₂O₇²⁻ is +6 and becomes +3 in Cr³⁺ (gains electrons, reduced), while I⁻ at -1 becomes I₂ at 0 (loses electrons, oxidized). Since I⁻ loses electrons (goes from -1 to 0), it is the species being oxidized. A common error is thinking Cr₂O₇²⁻ is oxidized because it's a complex ion, but we must track individual element oxidation states, not the overall charge. Remember: oxidation means loss of electrons (increase in oxidation number); the species being oxidized is the reducing agent.
Hydrogen peroxide decomposes according to the equation below:
$$2\text{H}_2\text{O}_2(aq)\rightarrow 2\text{H}_2\text{O}(l)+\text{O}_2(g)$$
Which statement correctly describes the redox changes of oxygen in this reaction?
Oxygen remains at oxidation number $-1$ throughout
Oxygen is both oxidized and reduced: $0\rightarrow -1$ and $-2\rightarrow -1$
Oxygen is both oxidized and reduced: $-1\rightarrow 0$ and $-1\rightarrow -2$
Oxygen is only oxidized: $-1\rightarrow 0$
Oxygen is only reduced: $-1\rightarrow -2$
Explanation
This question tests understanding of oxidation-reduction (redox) reactions. In 2H₂O₂(aq) → 2H₂O(l) + O₂(g), oxygen in H₂O₂ has oxidation number -1 (peroxide), and it changes to -2 in H₂O (gains 1 electron, reduced) and to 0 in O₂ (loses 1 electron, oxidized). This is a disproportionation reaction where the same element (oxygen) is both oxidized and reduced: -1 → 0 (oxidation) and -1 → -2 (reduction). A common error is thinking oxygen remains at -1 or only undergoes one type of change. Remember: in disproportionation reactions, the same element in one oxidation state produces two different oxidation states.
Chlorine gas is bubbled into an aqueous solution of potassium iodide, producing iodine and chloride ions:
$$\text{Cl}_2(g)+2\text{KI}(aq)\rightarrow 2\text{KCl}(aq)+\text{I}_2(s)$$
Which species is reduced in the reaction?
Cl$^-$(aq)
Cl$_2$(g)
I$^-$(aq)
K$^+$(aq)
I$_2$(s)
Explanation
This question tests understanding of oxidation-reduction (redox) reactions. In Cl₂(g) + 2KI(aq) → 2KCl(aq) + I₂(s), we track oxidation numbers: Cl₂ starts at 0 (elemental) and becomes Cl⁻ with oxidation number -1, while I⁻ (oxidation number -1) becomes I₂ at 0. Since Cl₂ gains electrons (0 to -1), it is reduced; I⁻ loses electrons (-1 to 0) and is oxidized. A common error is thinking I⁻ is reduced because it forms a solid, but physical state doesn't determine oxidation/reduction—only electron transfer does. Remember: reduction is gain of electrons (decrease in oxidation number); track the change in oxidation states, not physical states.
Nitrogen monoxide reacts with oxygen to form nitrogen dioxide:
$$2\text{NO}(g)+\text{O}_2(g)\rightarrow 2\text{NO}_2(g)$$
Which statement correctly describes the oxidation-number change for nitrogen?
Nitrogen changes from $+4$ in NO to $+2$ in NO$_2$
Nitrogen changes from $0$ in NO to $+2$ in NO$_2$
Nitrogen changes from $+2$ in NO to $+4$ in NO$_2$
Nitrogen changes from $-2$ in NO to $0$ in NO$_2$
Nitrogen remains $+3$ in both NO and NO$_2$
Explanation
This question tests understanding of oxidation-reduction (redox) reactions. In 2NO(g) + O₂(g) → 2NO₂(g), we must determine nitrogen's oxidation numbers: in NO, N is +2 (since O is -2 and the compound is neutral), and in NO₂, N is +4 (since 2×(-2) = -4 from oxygen requires N to be +4). Nitrogen changes from +2 to +4, losing 2 electrons per atom (oxidized). A common error is assuming N is +4 in NO because students might incorrectly think all nitrogen oxides have similar oxidation states. Remember: calculate oxidation numbers systematically using the rule that oxygen is typically -2 in compounds.
Nitrogen monoxide reacts with oxygen to form nitrogen dioxide, as shown:
$\mathrm{2,NO(g) + O_2(g) \rightarrow 2,NO_2(g)}$
How does the oxidation number of nitrogen change in this reaction?
It decreases from +2 to 0
It increases from 0 to +2
It remains +2
It increases from +2 to +4
It decreases from +2 to +1
Explanation
This question assesses understanding of oxidation–reduction (redox) reactions. To track nitrogen's oxidation number change, assign them: in NO(g), O is -2 so N is +2; O in O₂(g) is 0; in NO₂(g), O is -2 (total -4) so N is +4. Nitrogen's oxidation number increases from +2 to +4, showing loss of electrons and oxidation, while oxygen is incorporated but its role supports the change. The increase is from +2 to +4, not a decrease or no change. A tempting distractor is 'it decreases from +2 to 0,' but N goes to +4, not 0—a common error is miscalculating NO₂ as N at 0 by ignoring oxygen's contribution. Oxidation is loss of electrons; reduction is gain of electrons—track oxidation numbers carefully for polyatomic molecules.