AP Chemistry
Advanced Placement Chemistry exploring atomic structure, chemical bonding, and reactions.
Quantum Mechanical Model of the Atom
Beyond the Bohr Model
The quantum mechanical model describes electrons as existing in probability clouds called orbitals, not fixed paths. Electrons have certain allowed energies, and their exact locations can't be pinpointed—only the probability of finding them in a region.
Electron Configuration
- Electrons fill orbitals in a specific order (Aufbau principle).
- Pauli exclusion principle: No two electrons can have the same set of quantum numbers.
- Hund's rule: Electrons fill degenerate orbitals singly first.
Quantum Numbers
There are four quantum numbers that describe each electron:
- Principal (\( n \)): Energy level.
- Angular momentum (\( l \)): Shape of the orbital.
- Magnetic (\( m_l \)): Orientation.
- Spin (\( m_s \)): Direction of spin.
Real-World Relevance
Quantum mechanics explains why elements emit unique colors in fireworks and enables technologies like lasers and MRI machines.
Key Formula
\[E = h u\]
Examples
Neon signs glow red-orange because of electron transitions between energy levels.
MRI machines use quantum properties of nuclei to create medical images.
In a Nutshell
The quantum mechanical model uses probability to describe electrons in atoms.