All Organic Chemistry Resources
Example Questions
Example Question #1 : Help With Other Named Reactions
Why does the reaction above require the use of Ag2O?
The Ag2O reduces the alcohol to form the alkoxide ion
The Ag2O is an inert solvent and allows the alcohol to attack and from the product without interference
The Ag2O oxidizes the alcohol to form the alkoxide ion
The Ag2O attacks the alcohol to form the ether
The Ag2O oxidizes the alkyl halide to form the ether
The Ag2O oxidizes the alcohol to form the alkoxide ion
The Ag2O oxidizes the alcohol to form the alkoxide ion. The Ag2O is a reducing agent, and it oxidizes the alcohol because the alcohol loses a proton. Ag2O is a strong base, meaning it will accept protons readily. The given reaction is an example of Williamson ether synthesis. This reaction occurs via an SN2 pathway.
Example Question #2 : Help With Other Named Reactions
What is the IUPAC name of the following compound?
2-bromo-1-methylcyclohexene
1-bromo-2-methyl-2-cycloxene
3-bromo-2-methylcyclohexene
6-bromo-1-methylcyclohexene
None of the other answers
3-bromo-2-methylcyclohexene
The numbering of the molecule begins across the double bond and goes in the direction where the lowest numbers for substituents can be achieved. Thus, the methyl group will be on carbon two and the bromine on carbon 3. Substituents are ordered alphabetically. The base molecule is a six-membered ring with one double bond. This is called a cyclohexene.
Example Question #3 : Help With Other Named Reactions
What is the proper name of this molecule?
Z-2-isohexene
E-3-methyl-3-pentene
None of the other answers
E-2-ethyl-2-butene
E-3-methyl-2-pentene
E-3-methyl-2-pentene
The longest chain has five carbons and a double bond, so the base molecule is pentene. There is a methyl group on carbon 3. The double bond is between carbons two and three. The highest priority substituents are the ethyl group on one side and the methyl group on the other. One is up and one is down, so the molecule is E as opposed to Z.
Example Question #4 : Help With Other Named Reactions
Which of the following best summarizes the Michael reaction?
The enolate of a dicarbonyl compound attacks a beta carbon of an alkene
The enolate of an ester attacks another ester
An alkyl halide reacts first with the phthalimide ion, then with
A carboxylic acid reacts first with , then with water
A methyl ketone is treated with iodine and
The enolate of a dicarbonyl compound attacks a beta carbon of an alkene
The most acidic carbon in a dicarbonyl gets abstracted to form an enolate. The reaction involves a ketone with a double bond between the alpha and beta carbons. The carbon-carbon souble bond electrons attack the beta carbon of the alkene. At this point, the electrons from the alkene move to form a double bond between the carbonyl and alpha carbon and an enolate is fromed. The negative oxygen bonds to a hydrogen, forming the enol. Through enol-ketone tautamerization, a ketone is formed.
Example Question #5 : Help With Other Named Reactions
Which of the following best summarizes a Gabriel synthesis?
The enolate of an ester attacks another ester
A carboxylic acid reacts first with , then with water
The enolate of a dicarbonyl compound attacks a beta carbon of an alkene
An alkyl halide reacts first with the phthalimide ion, then with
A methyl ketone is treated with iodine and
An alkyl halide reacts first with the phthalimide ion, then with
An alkyl halide and phtalimide react under basic conditions to form a primary amine. The halogen leves and the nitrogen of the phtahlimide bonds to that carbon on the alkane. In the next step, the nitrogen leave the phthalimide. In the presence of base, the phthalimide gains two negative oxygens in the stead of the nitrogen. The final product is a primary amine.
Example Question #6 : Help With Other Named Reactions
For the given free radical halogenation reaction, which of the following is the product?
1.
2.
3.
4.
5.
2
In a free radical halogenation, a bromine group will form a bond with the most substituted carbon atom. This method leads to the most stable radical intermediate.
Example Question #6 : Help With Other Named Reactions
Which of the following is the correct IUPAC name for the compound given?
2-methyl-4-ethylpentanal
2-methyl-4-hexanal
2-ethyl-4-methylpentanal
2-ethyl-4-methylpentanal
2-ethyl-4-methylpentanal
The compound given has an aldehyde functional group and the parent chain has to have the -CHO group. Below is how the compound given should be numbered:
Aldehydes are named by changing the ending -e from the corresponding alkane with -al. The substituents on the parent chain should be named in alphabetical order. Therefore the answer is 2-ethyl-4-methylpentanal.
Example Question #7 : Help With Other Named Reactions
Which of the following is the correct IUPAC name for the compound given?
4-methyl-3-chlorolhexanol
4-chloro-6-hydroxy-3-methylhexane
4-chloro-3-methylhexanol
3-chloro-4-methylhexanol
3-chloro-4-methylhexanol
The compound given has an alcohol functional group and the parent chain has to have the hydroxyl functional group. Below is how the compound given should be numbered:
Alcohols are named by changing the ending -e from the corresponding alkane with -ol. The substituents on the parent chain should be named in alphabetical order. Therefore the answer is 3-chloro-4-methylhexanol.
Example Question #8 : Help With Other Named Reactions
Which of the following is the correct IUPAC name for the compound given?
4,5-dibromo-4-methylhexane
4-methy-4,5-dibromolhexane
4-methyl-2,3-dibromohexane
2,3-dibromo-4-methylhexane
2,3-dibromo-4-methylhexane
We have to find the longest chain to name it as the parent chain starting at the end with the nearest the substituent. Below is how the compound given should be numbered:
The substituents on the parent chain should be named in alphabetical order and because we have 2 bromine substituents we must add the name di-bromo and add the number of the carbon atom on the parent chain in which they appear. Therefore the answer is 2,3-dibromo-4-methylhexane.
Example Question #10 : Help With Other Named Reactions
Predict the product of the chemical reaction given.
The reaction given is called a Fischer esterification reaction. It is a reaction between an alcohol and a carboxylic acid to form an ester. Carboxylic acids are not reactive enough to be attacked by an alcohol so the reaction requires a strong acid catalyst like hydrochloric acid for the reaction to occur. Below is the mechanism:
Certified Tutor
Certified Tutor