All AP Chemistry Resources
Example Questions
Example Question #25 : Chemical Equilibrium
Which of the following will cause an equilibrium shift in an exothermic reaction towards the products?
I. Decreasing the temperature
II. Evaporating the product
III. Adding a catalyst
I and III only
I and II only
I, II, and III only
I only
III only
I and II only
I) Decreasing the temperature would take away heat from the system (a product), driving the reaction towards the products. II) Evaporating product would take a product away from the system, driving the reaction towards the products. III) Adding a catalyst only affects the rate of the reaction and does not effect equilibrium.
Example Question #1 : Le Chatelier's Principle
According to Le Chatelier's principle, which of the following occurs when you compress a system containing at least one gas species?
remains at equilibrium
shifts to favor the side with more moles of gas
not enough information to determine
shifts to favor the side with less moles of gas
shifts to favor the side with less moles of gas
According to Le Chatelier's principle, when you compress a system, its volume decreases, so partial pressure of the all the gases in the system increases. The system will act to try to decrease the pressure by decreasing the moles of gas.
Example Question #2 : Le Chatelier's Principle
If heat is added to an endothermic reaction, in which direction will the equilibrium shift according to Le Chatelier's principle?
equilibrium does not shift
cannot be determined
to the left
to the right
to the right
In an endothermic reaction, heat can be treated as a reactant. Thus, if you add more reactant (heat), the system will shift to get rid of the extra reactant and shift to the right to form more products.
Example Question #3 : Le Chatelier's Principle
If heat is added to an exothermic reaction, in which direction will the equilibrium shift according to Le Chatelier's principle?
It cannot be determined.
It shifts to the left.
Equilibrium does not shift.
It shifts to the right.
It shifts to the left.
In an exothermic reaction, heat can be treated as a product. Thus, if you add more product (heat), the reaction will shift to the left to form more reactants.
Example Question #1 : Le Chatelier's Principle
Which of the following stresses would lead the exothermic reaction below to shift to the right?
Decreasing the volume
Increasing [C]
Increasing the temperature
Increasing [A]
Increasing [A]
By increasing the concentration of one of the reactants, the reaction will compensate by shifting to the right to increase production of products.
Increasing the concentration of one of the products (such as increasing [C]), however, would have the opposite effect. Increasing the temperature of an exothermic reaction would shift the reaction to the left, while increasing the temperature of an endothermic reaction would lead to a rightward shift. Finally, decreasing the volume leads to an increase in partial pressure of each gas, which the system compensates for by shifting to the side with fewer moles of gas. In this case, the right side has three moles of gas, while the left side has two; thus decreasing volume would shift equilibrium to the left.
Example Question #1 : Le Chatelier's Principle
Figure 1: Ammonia gas formation and equilibrium
What would most likely happen if a scientist decreased the volume of the container in which the reaction occurs?
More NH3 would form
Less NH3 would form
A violent explosion would occur
More H2 would form
More N2 would form
More NH3 would form
Le Chatelier's principle states that changes in pressure are attributable to changes in volume. If we increase the volume, the reaction will shift toward the side that has more moles of gas. If we decrease the volume, the reaction will shift toward the side that has less moles of gas. Since the product side has only two moles of gas, compared to the reactant side with four moles, the reaction would shift toward the product side, and more NH3 would form.
Example Question #2 : Le Chatelier's Principle
Which of the following reactions will be favored when the pressure in a system is increased?
I.
II.
III.
I, II, and III
II and III only
II only
I and II only
I only
II only
With increased pressure, each reaction will favor the side with the least amount of moles of gas. In this problem we are looking for the reactions that favor the products in this scenario. I will favor reactants, II will favor products, III will favor reactants.
Example Question #7 : Le Chatelier's Principle
Consider the following reaction system, which has a Keq of 1.35 * 104, taking place in a closed vessel at constant temperature.
Which of the following is NOT true about this system at equilibrium?
Increasing the pressure will produce more AX5
Increasing the volume will produce more AX5
AX5 is the main compound present
The rate of formation of AX5 equals the rate of formation of AX3 and X2
Increasing the volume will produce more AX5
An increase in volume will result in a decrease in pressure at constant temperature. As a result, the equilibrium will shift toward the side with the greater total moles of gas, according to Le Chatelier's Principle. This will result in less AX5 being produced.
The Keq tells us that the reaction favors the products because it is greater than 1. The definition of equilibrium is that the rate of formation of products equals the rate of formation of reactants.
Example Question #5 : Le Chatelier's Principle
What would happen to the Ksp if NH3 was added to an existing solution of Na2SO4?
It woud remain unchanged.
It is impossible to determine.
It would increase.
It would decrease.
It woud remain unchanged.
Ksp is dependent only on the species itself and the temperature of the solution. Adding another compound or stressing the system will not affect Ksp.
Example Question #1 : Le Chatelier's Principle
Which of the following would occur if NH3 was added to an existing solution of Na2SO4?
No effect
Additional Na2SO4 will precipitate
Na2SO4 will dissolve more
It is impossible to determine
Additional Na2SO4 will precipitate
Both Na2SO4 and ammonia are slightly basic compounds. Thus, adding ammonia will create a common ion effect, where less sodium sulfate will be able to dissolve and some would precipitate out of solution.
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