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Example Questions
Example Question #1 : Orbitals And Hybridization
What is the hybridization on the nitrogen atom in a molecule of ammonia?
sp2
sp3d
sp3
sp
sp3
The hybridization of an atom can be determined by the number of atoms it is bonded to, as well as the number of lone pairs it has. Two of these variables would be sp, three variables would be sp2, and four would be sp3.
The nitrogen in ammonia is bonded to three atoms of hydrogen, but also has a lone pair in order to satisfy its octet. This means that nitrogen exhibits sp3 hybridization.
Example Question #41 : Nuclear, Quantum, And Molecular Chemistry
Which of the following are true regarding and
orbitals?
I. Both and
orbitals can contain a maximum of two electrons
II. In a given shell, orbitals are more numerous because they are spherical in shape
III. orbitals have lower energy than
orbitals within the same shell
I and III
I only
III only
I and II
I and III
Orbitals are regions in an electron shell where electrons might be located. There are several types of orbitals such as , and
. Most elements found on the periodic table contain electrons within one of these orbitals. A characteristic of an orbital is that it can only contain two electrons maximum. A shell might contain multiple orbitals; however, each orbital can only contain two electrons. Each orbital has a unique shape that corresponds to the electron density (the possible location of an electron at a given point in time). The
orbital has a spherical shape whereas the
orbital has a dumbbell shape. As mentioned, a shell can contain multiple types of orbitals. A shell can typically contain one
orbital, three
orbitals, five
orbitals, and seven
orbitals. Remember that the shape of the orbital has no bearing on the amount of orbitals in a shell. An orbital is higher in energy if it is found farther away from the nucleus. The orbitals in order of increasing energy is as follows
. Therefore, an
orbital has lower energy than a
orbital in the same shell.
Example Question #42 : Nuclear, Quantum, And Molecular Chemistry
What is true when comparing the electron configuration of elemental sodium and sodium cation
?
The sodium ion has more electrons in orbitals
The outermost shell of the sodium ion has one electron
Elemental sodium is paramagnetic
The sodium ion has one additional electron in an orbital
Elemental sodium is paramagnetic
To answer this question, we need to find the electron configuration of both elemental sodium and sodium cation. If we look at the periodic table we can see that sodium is found on the first column. Since it is found in the first column, sodium has one valence electron. To complete octet, sodium will readily lose an electron and become a positively charged sodium ion. The electron configuration for sodium is . The electron configuration for sodium ion is
(because it lost its electron in the
orbital). This means that elemental sodium has an unpaired electron in its
orbital; the sodium ion has no unpaired electrons. Recall that an unpaired electron can generate its own magnetic field and is called paramagnetic; therefore, solid sodium is paramagnetic. The number of electrons in the
orbitals for both sodium and sodium ion is the same (6 electrons total in the
orbital). The outermost shell of sodium is the third shell (because sodium is located on the third row of periodic table). Elemental sodium contains one electron in the
orbital in the outermost shell whereas the sodium ion contains 6 electrons in its outermost shell.
Example Question #42 : Nuclear, Quantum, And Molecular Chemistry
It is observed that a molecule has three hybridized orbitals in its outermost shell. What can you conclude about this molecule?
It has a lone pair electron
It has four single bonds
None of these
It has a double bond
It has a double bond
Hybridization is a process involving the fusion, or hybridization, of and
orbitals to form a unique orbital. It is possible for various combinations of
and
hybridization. Recall that there is one
orbital and three
orbitals in each shell. This means that the one
orbital can hybridize with 1, 2, or all 3
orbitals. Since there are three total combinations, there are three types of hybridized orbitals. These are
,
, and
.
orbital has one
and one
orbital hybridized. This means that the
orbital and the first
orbital become a new
orbital. A molecule with
hybridization will have two
orbitals and two
orbitals. Similarly, an
orbital is made from the hybridization of one
and two
orbitals. In
hybridization, there are three
orbitals and one
orbital. Finally, an
orbital has one
and all three
orbitals; therefore, an
hybridized molecule will have four
orbitals and no
orbitals. The question states that there are three hybridized orbitals in this molecule; therefore, this molecule must be
hybridized. The single
orbital is unhybridized because the molecule probably has a double bond. Electrons in
bonds in double and triple bonds cannot be found in hybridized orbitals; therefore, they need their own
orbital. If a molecule has one
bond (double bond), then it will need one
orbital and will be
hybridized (because this will give three
hybridized orbitals and one
orbital). If it has two
bonds (triple bond), then it will need two
orbitals and will be
hybridized. If a molecule has all
bonds (single bonds), then the molecule will require no empty
orbitals for the delocalized electrons, and will be
hybridized.
Example Question #43 : Nuclear, Quantum, And Molecular Chemistry
Which of the following is true regarding carbon tetrachloride?
More than one of these are true
The carbon in this molecule has similar hybridization as the carbon in carbon dioxide
Hybridization in this molecule involves three times as many orbitals as
orbitals
Hybridization in this molecule involves two times as many orbitals as
orbitals
Hybridization in this molecule involves three times as many orbitals as
orbitals
Carbon tetrachloride, , has a central carbon atom attached to four chlorine atoms. The bonds between the carbon atom and chlorine atoms are single covalent bonds. The electrons in a single bond (
bond) can be found in hybridized orbitals. Since carbon tetrachloride only has single bonds, the carbon atom can hybridize all of its orbitals (one
and three
) in the outermost shell and form a
hybridization; therefore, three
orbitals and one
orbital participate in hybridization leading us to the correct answer. Carbon dioxide,
, has a central carbon atom bonded to two oxygen atoms. To complete octet, carbon and oxygen atoms have double bonds. This means that carbon dioxide has two
bonds (two double bonds). Recall that electrons in
bonds cannot reside in hybridized orbitals; therefore, to accommodate the two
bonds we need two empty, unhybridized
orbitals. This means that carbon dioxide will have hybridization of one
and one
orbital, giving it an
hybridization.
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