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College Chemistry : Common Ion Effect

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Example Question #1 : Common Ion Effect

Calculate the molar solubility of barium fluoride when it is dissolved in a solution containing 0.200M of sodium fluoride. Barium fluoride has a $\text{K}_{sp}$ value of $2.45\times 10^{-5}$ .

Possible Answers:

$6.05\times 10^{-4} M$

$7.21\times 10^{-2} M$

$2.09\times 10^{-8} M$

$1.44\times 10^{-5} M$

Correct answer:

$6.05\times 10^{-4} M$

Explanation:

Start by writing out the equation for the dissolution of barium fluoride.

$\text{BaF}_2(s)\rightleftharpoons\text{Ba}^{2+}(aq)+2\text{F}^-(aq)$

Next, write out the chart to keep track of concentrations of each ion.

	[ $Ba^{2+}$ ]	[]
Initial	0.00	0.200
Change	+x	+2x
Equilibrium	x	0.200+2x

In the chart, is the amount of barium fluoride that dissolves. Since we are putting barium fluoride in a solution of 0.200M sodium fluoride, the initial concentration of the fluoride ion is 0.200M . Since there is already some fluoride in the solution, we should expect that the molar solubility of barium fluoride should be less than its molar solubility when dissolved in water.

Now, write the equilibrium expression using the chemical equation:

$\text{K}_{sp}=[\text{Ba}^{2+}][\text{F}^-]^2$

Plug in the given $\text{K}_{sp}$ and solve for .

$2.45\times10^{-5}=(0.200+2x)^2(x)$

At this point, use a graphing calculator to solve for .

$x=6.05\times10^{-4}$

The molar solubility of barium fluoride in sodium fluoride is $6.05\times10^{-4}M$ .

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Example Question #12 : Equilibrium

Suppose that a chemist wants to lower the concentration of calcium in an aqueous solution by precipitating it out, according to the following reaction expression.

$Ca(OH)_{2}(s)\rightleftharpoons Ca^{2+}(aq)+2OH^{-}(aq)$

Which of the following chemicals could the chemist add to the solution in order to precipitate the calcium?

Possible Answers:

Any of these

HCl

NaCl

$CaCl_{2}$

NaOH

Correct answer:

NaOH

Explanation:

In this question, we're shown an equilibrium expression for a precipitation reaction in solution. We're asked to identify a compound that will help calcium precipitate out of solution.

To identify a compound that will precipitate calcium out of solution, we need to consider the equilibrium expression shown in the question stem. Applying Le Chatlier's principle, we'll need to consider the direction each of the answer choices will push the reaction in.

Adding HCl will make the solution more acidic. As a result, there will be a decreased amount of $OH^{-}$ . Consequently, the reaction will shift to the right and there will be more calcium in solution.

Adding $CaCl_{2}$ will drive up the concentration of calcium, which will drive the reaction to the left. Even though this will cause calcium to precipitate out of the solution, it nonetheless defeats the purpose because the amount of dissolved calcium in solution is not decreasing.

Adding NaCl to the solution will have no effect on the reaction equilibrium because neither of the ions appears in the expression.

Adding NaOH will cause the solution to become more basic, with an increased amount of $OH^{-}$ . Consequently, the reaction equilibrium will be driven toward the left. This will, in turn, cause calcium to precipitate out of solution in the form of the solid $Ca(OH)_{2}$ .

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College Chemistry : Common Ion Effect

Study concepts, example questions & explanations for College Chemistry

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Example Question #1 : Common Ion Effect

Example Question #12 : Equilibrium

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