High School Chemistry : Balancing Reactions

Study concepts, example questions & explanations for High School Chemistry

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Example Questions

Example Question #1 : Balancing Oxidation Reduction Reactions

What is the coefficient on sulfur dioxide if the following redox reaction is balanced in an acidic solution?

\displaystyle SO_{2} + Cr_{2}O_{7}^{2-} \rightarrow SO_{4}^{2-} + Cr^{3+}

Possible Answers:

\displaystyle 2

\displaystyle 3

\displaystyle 5

\displaystyle 4

Correct answer:

\displaystyle 3

Explanation:

Balancing redox reactions involves the following steps:

1. Divide the reaction into oxidation and reduction half reactions and balance all atoms that are not oxygen and hydrogen:

\displaystyle SO_{2} \rightarrow SO_{4}^{2-}

\displaystyle Cr_{2}O_{7}^{2-} \rightarrow 2Cr^{3+}

2. Balance the oxygens by adding water molecules on the opposite side of the reactions:

\displaystyle 2H_{2}O + SO_{2} \rightarrow SO_{4}^{2-}

\displaystyle Cr_{2}O_{7}^{2-} \rightarrow 2Cr^{3+} + 7H_{2}O

3. Balance the hydrogens by adding protons to the opposite side of the equation:

\displaystyle 2H_{2}O + SO_{2} \rightarrow SO_{4}^{2-} + 4H^{+}

\displaystyle 14H^{+} + Cr_{2}O_{7}^{2-} \rightarrow 2Cr^{3+} + 7H_{2}O

4. Add electrons in order to equal the charges on both sides of the equation:

\displaystyle 2H_{2}O + SO_{2} \rightarrow SO_{4}^{2-} + 4H^{+} + 2e^{-}

\displaystyle 6e^{-} + 14H^{+} + Cr_{2}O_{7}^{2-} \rightarrow 2Cr^{3+} + 7H_{2}O

5. In order to make the electron exchange equal in each half step, we must multiply the top half reaction by 3:

 \displaystyle 6H_{2}O + 3SO_{2} \rightarrow 3SO_{4}^{2-} + 12H^{+} + 6e^{-}

\displaystyle 6e^{-} + 14H^{+} + Cr_{2}O_{7}^{2-} \rightarrow 2Cr^{3+} + 7H_{2}O

6. Add up the reactants and products while cancelling out substances on opposite sides of the reactions. For example: we will cancel the 6 water molecules as reactants and be left with only one water molecule as a product. In addition, only 2 protons will be left on the reactant's side after canceling the 12 from the product's side.

\displaystyle Cr_{2}O_{7}^{2-} + 3SO_{2} + 2H^{+} \rightarrow 2Cr^{3+} + 3SO_{4}^{2-} + H_{2}O

In the balanced redox reaction, the coefficient on sulfur dioxide is 3.

Example Question #301 : Ap Chemistry

For the following unbalanced redox reaction, how many electrons are transferred and which chemical species is being oxidized?

Possible Answers:

One electron is transferred; P is oxidized

Two electrons are transferred; Hg is oxidized

One electron is transferred; Hg is oxidized

Two electrons are transferred; P is oxidized

Correct answer:

Two electrons are transferred; Hg is oxidized

Explanation:

To begin, we will need to separate the given reaction into the two half-reactions by identifying changes in oxidation number. In this case, mercury (Hg) and phosphorus (P) show a change in oxidation number. Mercury begins with an oxidation number of zero, and ends with an oxidation number of \displaystyle +1. Phosphorus begins with an oxidation number of \displaystyle +3 and ends with an oxidation number of \displaystyle +2. Note that the oxidation numbers for fluorine and iodine reamain constant at \displaystyle -1 for each.

Now we can begin to look at the half-reactions.

Balance the atoms.

Now balance the electrons. We know that each mercury atom loses one electron and each fluorine atom gains one electron.

We can see that two electrons are tranferred. To identify the element being oxidized, we must find the element that is losing electrons. In this case, mercury is being oxidized.

Example Question #1 : Balancing Reactions

Oxidation is the __________ of electrons, reduction is the __________ of electrons.

Possible Answers:

gain . . . loss

None of these; it depends on the reaction.

loss . . . gain

gain . . . gain

loss . . . loss

Correct answer:

loss . . . gain

Explanation:

An oxidation-reduction (redox) reaction is a reaction where electrons are transferred between two substances. When an atom is oxidized, it is called the reducing agent, and it loses a number of electrons. Similarly, a reduced atom is called the oxidizing agent, and gains the same number of electrons. A popular mnemonic to help remember is OIL RIG, or Oxidation is Loss of electrons, Reduction is Gain of electrons.

Example Question #922 : Ap Chemistry

What is the formula for the dissociation of iron (II) phosphate?

Possible Answers:

\displaystyle FeP\rightleftharpoons Fe^{2+}+P^{2-}

\displaystyle Fe_2(PO_4)_3\rightleftharpoons 2Fe^{3+}+3PO_4^{2-}

\displaystyle FePO_4\rightleftharpoons Fe^{2+}+PO_4^{2-}

\displaystyle Ir_3(PO_4)_2\rightleftharpoons 3Fe^{2+}+2PO_4^{3-}

\displaystyle Fe_3(PO_4)_2\rightleftharpoons 3Fe^{2+}+2PO_4^{3-}

Correct answer:

\displaystyle Fe_3(PO_4)_2\rightleftharpoons 3Fe^{2+}+2PO_4^{3-}

Explanation:

Iron (II) has a positive two charge: \displaystyle Fe^{2+}.

Phosphate has a negative three charge: \displaystyle PO_4^{3-}.

The initial compound must be constructed to cancel these charges. The dissociation is: \displaystyle Fe_3(PO_4)_2\rightleftharpoons 3Fe^{2+}+2PO_4^{3-}.

Example Question #3 : Balancing Equations

Calcium hydroxide is treated with hydrochloric acid to produce water and calcium chloride. Write a balanced chemical reaction that describes this process.

Possible Answers:

\displaystyle Ca(OH)_{2} + HCl \rightarrow H_{2}O + CaCl_{2}

\displaystyle CaOH + HCl \rightarrow H_{2}O + CaCl

\displaystyle Ca(OH)_{2} + 2HCl \rightarrow 2H_{2}O + CaCl_{2}

\displaystyle 2Ca(OH)_{2} + HCl \rightarrow H_{2}O + 2CaCl_{2}

\displaystyle Ca(OH)_{3} + 3HCl \rightarrow 3H_{2}O + CaCl_{3}

Correct answer:

\displaystyle Ca(OH)_{2} + 2HCl \rightarrow 2H_{2}O + CaCl_{2}

Explanation:

Calcium is in the second group of the periodic table, and is therefore going to have a \displaystyle \small +2 oxidation number. Hydroxide ions have a \displaystyle \small -1 charge. Calcium hydroxide will have the formula \displaystyle \small Ca(OH)_2.

Chloride ions have a \displaystyle \small -1 charge and hydrogen ions have a \displaystyle \small +1 charge. The formula for hydrochloric acid is \displaystyle \small HCl.

On the products side, water has the formula \displaystyle \small H_2O and calcium chloride has the formula \displaystyle \small CaCl_2.

Now that we know all of the formulas, we can write our reaction:

\displaystyle Ca(OH)_2+HCl\rightarrow H_2O+CaCl_2

In order to balance the chloride atoms, we need to add coefficients.

\displaystyle Ca(OH)_2+2HCl\rightarrow 2H_2O+CaCl_2

Example Question #1 : Balancing Chemical Equations

What is the coefficient for oxygen gas when the following equation is balanced?

\displaystyle C_{5}H_{12} + O_{2} \rightarrow CO_{2} + H_{2}O

Possible Answers:

\displaystyle 10

\displaystyle 5

\displaystyle 8

\displaystyle 4

Correct answer:

\displaystyle 8

Explanation:

The balanced reaction for the combustion of pentane is:

\displaystyle C_{5}H_{12} + 8O_{2} \rightarrow 5CO_{2} + 6H_{2}O

When balanced, oxygen gas has a coefficient of eight.

To balance the equation, it is easiest to leave oxygen and hydrogen for last. This means we should start with carbon.

\displaystyle C_{5}H_{12} + O_{2} \rightarrow CO_{2} + H_{2}O

\displaystyle C_{5}H_{12} + O_{2} \rightarrow 5CO_{2} + H_{2}O

Now that carbon is balanced, we can look at hydrogen.

\displaystyle C_{5}H_{12} + O_{2} \rightarrow 5CO_{2} + 6H_{2}O

Finally, we can balance the oxygen.

\displaystyle C_{5}H_{12} + 8O_{2} \rightarrow 5CO_{2} + 6H_{2}O

The final reaction uses five carbon atoms, twelve hydrogen atoms, and sixteen oxygen atoms per side.

Example Question #2 : Balancing Chemical Equations

Given the unbalanced reaction below, how many moles of solid iron can be made from ten moles of iron oxide?

Possible Answers:

\displaystyle 20 mol

\displaystyle 2 mol

\displaystyle 1 mol

\displaystyle 5 mol

\displaystyle 10 mol

Correct answer:

\displaystyle 20 mol

Explanation:

The balanced chemical equation is:

The mole ratio of iron oxide to solid iron is 1:2. You can set up the following proportion to solve:

\displaystyle \frac{1mol\ Fe_2O_3}{2mol\ Fe}=\frac{10mol\ Fe_2O_3}{x}

\displaystyle x = (2)(10) = 20 mol\ Fe

Example Question #3 : Balancing Chemical Equations

What is the chemical formula of the salt formed when a chemist mixes solvated Potassium and Arsenic ions in solution?

Possible Answers:

K_3As\displaystyle K_3As

KAs\displaystyle KAs

K_2As\displaystyle K_2As

KAs_2\displaystyle KAs_2

KAs_3\displaystyle KAs_3

Correct answer:

K_3As\displaystyle K_3As

Explanation:

Potassium is a Group I element, so to get to a filled valence shell, it will lost one electron, yielding K^+\displaystyle K^+.

Arsenic is a Group 5 element, so it needs to gain three electrons to obtain a filled valence shell, yielding As^{-3}\displaystyle As^{-3}.

In order to balance out the charges, the resultant salt will be K_3As\displaystyle K_3As.

Example Question #1 : Introduction For Reactions

What is the net ionic equation for the ion exchange reaction between ferrous sulfate and calcium iodide? Assume all compounds are soluble.

Possible Answers:

None of the available answers

\displaystyle Fe(SO_4)_2 + CaI_2 \rightarrow FeI_2 +Ca(SO_4)_2

\displaystyle FeSO_4 + CaI_2 \rightarrow FeI_2 +CaSO_4

\displaystyle Fe_2SO_4 + CaI_2 \rightarrow 2FeI +CaSO_4

\displaystyle FeSO_4 + CaI \rightarrow FeI +CaSO_4

Correct answer:

\displaystyle FeSO_4 + CaI_2 \rightarrow FeI_2 +CaSO_4

Explanation:

First, we must know what ferrous sulfate is. Ferrous refers to \displaystyle Fe^{2+} , and sulfate has the formula \displaystyle SO_4^{-2}. When we combine the two together we get \displaystyle FeSO_4.

Calcium is a divatent cation and iodide is a monovalent anion, so their salt is \displaystyle CaI_2. The ion exchange reaction is then:

\displaystyle FeSO_4 + CaI_2 \rightarrow FeI_2 +CaSO_4

Example Question #991 : Ap Chemistry

Select the net ionic equation from this molecular reaction:

\displaystyle Ba(NO_{3})_{2} (aq) + K_{2}SO_{4} (aq) \rightarrow 2KNO_{3} (aq) + BaSO_{4} (s)

Possible Answers:

\displaystyle Ba^{2+} (aq) + SO_{4}^{2-} (aq) \rightarrow BaSO_{4} (s)

None of the other choices

\displaystyle K^{+} (aq) + NO_{3}^{-} (aq) \rightarrow KNO_{3} (aq)

\displaystyle Ba^{2+} (aq) + 2K^{+} (aq) + SO_{4}^{2-} (aq) \rightarrow 2K^{+} (aq) + BaSO_{4} (s)

\displaystyle 2K^{+} (aq)+SO_{4}^{2-}(aq)\rightarrow K_{2}SO_{4} (aq)

Correct answer:

\displaystyle Ba^{2+} (aq) + SO_{4}^{2-} (aq) \rightarrow BaSO_{4} (s)

Explanation:

The net ionic equation is derived by removing all spectator ions from the total ionic equation (in which all ions are listed). To put it another way, the net ionic equation involves only the ions that participate in a reaction which, in this case, is the precipitation of barium sulfate.

Begin by writing all aqueous compounds in their dissociated (ionic) forms.

\displaystyle Ba(NO_{3})_{2} (aq) + K_{2}SO_{4} (aq) \rightarrow 2KNO_{3} (aq) + BaSO_{4} (s)

\displaystyle Ba^{2+}+2NO_3^-+2K^++SO_4^{2-}\rightarrow2K^++2NO_3^-+BaSO_4(s)

Cancel out any ions that appear in equal quantities on both sides of the equation. In this case, we can cancel the nitrate and potassium ions.

\displaystyle Ba^{2+}+SO_4^{2-}\rightarrow BaSO_4(s)

This is our net ionic equation.

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